Shape-controlled synthesis of Cu 2O nanocrystals assisted by PVP and application as catalyst for synthesis of carbon nanofibers

Abstract

In this paper, cuprous oxide (Cu 2O) nanostructures with different shapes, such as spheres, cubes and rods, have been synthesized by reducing copper nitrate trihydrate with ethylene glycol in the present of poly(vinylypyrrolidone) (PVP). The molar ratio of PVP (in the repeating unit) /Cu(NO 3) 2·3H 2O and reaction temperature have significant effects on the formation and growth of these Cu 2O nanostructures. The Cu 2O nanorods were fabricated at the molar ratios of PVP/Cu(NO 3) 2·3H 2O 2–3, while spherical and cubic nanoparticles were formed at the ratios of PVP/Cu(NO 3) 2·3H 2O 5–7 and 10–15. Increasing with reaction temperatures, monodisperse particles were obtained. The as-synthesized nanoparticles and nanorods were investigated by transmission electron microscopy (TEM), and field emission scanning electron microscopy (FE-SEM) and X-ray diffractometry (XRD). With the as-prepared nanoparticles as catalyst, carbon nanofibers (CNFs) were synthesized by catalytic polymerization of acetylene at a lower temperature (250 °C). The effects of the catalyst particle sizes on the morphologies of the carbon fibers were studied.