Abstract
With the consideration of a mobile high-viscosity water film and a bulk water layer, an analytical model is proposed to predict gas flow behaviors and gas apparent permeability in nanopores. Physical molecular forces are analyzed to determine the properties and formation of the high-viscosity water film and the bulk water layer. Boundary conditions at a solid-liquid interface and a liquid-gas interface are modified to account for water slippage and gas slip. How mobile bulk water molecules influence gas transport capability in pores of different geometry is investigated with different pore sizes and pressure for the whole range of water saturation, which has been validated with experimental data and simulation results. Besides, the effect of a wedged pore structure on multiphase flow behaviors is also investigated to figure out the influences of pore shape.
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