Abstract

Low-lying vacant molecular orbitals may lead not only to a breakdown of Koopmans' theorem but also to satellite structure in photoelectron spectra. This paper reports examples of the relatively infrequent appearance of shake-up satellites in Hel photoelectron spectra, namely those of N 2O 4 and CH 3NO. An extended version of the HAM/3 program was used to interpret these spectra.

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