Abstract

Electron attachment to mixed rare gas/SF 6 clusters — in contrast to pure SF 6 clusters — shows for the production of SF − 6 ions, besides the zero energy resonance, an additional resonance peak at higher electron energies in the attachment cross-section function. The process of SF − 6 production via this new resonance channel involves a multiple collision electron scavenging mechanism followed by an excimer-(R 2 ★) induced decay of an intermediate complex ion (R m ·R 2 ★SF − 6 plus neutral products.

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