Abstract
Three electrochemical methods for the simultaneous measurement of thermodynamic activity and the effective kinetic properties of inserted ions Solid Solution Electrode powder compacts are presented. The theoretical substructure of these methods, and the practical application on the systemsAg/Ag xTiS 2/Ag(0<x<1, T=193°C),Li/Li xCoO 2(0.96<x<1, T=20°C), resulting in values for both the chemical diffusion coefficient and the Darken factor of the inserted ions, are discussed.
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