Abstract
[reaction: see text] A novel three-component cyclization using allenylboronate ester is described. A three-component assembly of allenylboronate ester, aryl iodides, and stabilized carbon nucleophiles took place in the presence of palladium catalyst, furnishing functionalized alkenylboronate esters with high regio- and stereoselectivity. A Rh-catalyzed cyclization of the resultant three-component products then afforded interesting carbocyclic frameworks efficiently.
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