Sequential low-temperature depolymerization and liquefaction of US coals. Progress report No. 2, January 1--March 31, 1987

Abstract

One of the main objectives of this project is to investigate the low temperature ({le} 290{degrees}C) depolymerization-liquefaction reactions of representative US coals using a 3-step procedure recently developed in our Laboratory. The procedure involves subjecting the coal first to two consecutive depolymerization steps in which different types of intercluster linkages are subjected to preferential cleavage. The depolymerized products obtained have low molecular weights and consist predominantly of monocluster compounds. In the third step of the procedure these simplified depolymerization products are subjected to hydroprocessing and attendant exhaustive hydrodeoxygenation to yield light liquid hydrocarbon mixtures as main products. It is planned under the research program to adapt and optimize the above indicated procedure for US coals of different rank, and to examine the feasibility of the new processing concept for conversion of these coals into light liquid hydrocarbon fuels. A second major objective of the research program is to subject the lowtemperature depolymerization products (obtained by the first two consecutive steps) to exhaustive structural analysis for the purpose of deriving average structural models for the coals under investigation. Such models are expected to be useful as fingerprints for identification and differentiation of various representative US coals.