Sequential effects of two cations on the fluorescence emission of a coordination polymer with Zn4O core in node.

Abstract

Distinct changes in the fluorescence emissions of free ligand 5-(1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)isophthalic acid (H2NAPHISO) than a 2D-zinc-coordination polymer of it, caused by sequential interactions with different sets of binary cations were observed. The coordination polymer having unsymmetrical Zn4O core of tetranuclear zinc-node could be dispersed in dimethylformamide without its degradation. The coordination polymer had an emission peak at 435 nm (quantum yield = 0.082) which was selectively quenched by adding Fe2+ ions. Based on this quenching, the Fe2+ ions in aqueous solution could be detected with a detection limit 42.57 nM. The metal ions such as Li+, Na+, Cd2+, Hg2+, Al3+ did not interfere in the detection; but each of these ions together with Fe2+ ions showed characteristic shift of the emission spectra. The H2NAPHISO in dimethyl formamide was non-fluorescent, but showed emission at 452 nm upon addition of Cd2+ or Zn2+ ions. This new emission of H2NAPHISO caused by zinc or cadmium ions was not quenched by Fe2+ ions. Various cations had affected the emission of the H2NAPHISO with Zn2+ which was much different from the corresponding changes caused by the same ion on the emission of the coordination polymer. For example, the Mn2+ and Zn2+ ions together in a solution of the ligand showed a broad emission spectrum spreading over 380-450 nm, but ions Sn2+ and Zn2+ together had showed emission at a shorter wavelength (380 nm). These allowed to modulate the emission of the ligand by binary combination of metal ions.