Separation of organic contaminant (dye) using the modified porous metal-organic framework (MIL)

Abstract

Herein, the porous metal-organic framework (MIL-88B: Materials Institute Lavoisier) was synthesized and identified by FT-IR (Fourier transform infrared), SEM (Scanning Electron Microscopy), EDS (Energy Dispersive X-Ray Spectroscopy), and XRD (X-ray powder diffraction) analyses. Then MIL-88B was modified using 3-aminopropyl trimethoxy silane and presented as NH2-MIL-88B. The synthesized materials were used to separate direct red dye 23 (DR23) as an organic contaminant from water. The effect of various important factors such as the amount of adsorbent, initial concentration of contaminants, and pH was investigated. The results showed that the modified adsorbent (NH2-MIL-88B) had a higher adsorption capacity than the row adsorbent (MIL-88B). The amount of dye adsorption is high at lower pH values. The percentage of DR23 dye removal was complete under optimal conditions. Increasing the amount of adsorbent (0.001–0.003 g) and decreasing the pH (2.1–8.1) increases the percentage of dye removal and increasing the concentration of contaminant (50–125 mg/L) reduces the dye removal in the process. Isotherm data showed that the adsorption process followed the Langmuir model. Also, pseudo-first-order, pseudo-second-order, and intraparticle diffusion kinetic models were used to investigate the adsorption kinetics. Dye adsorption followed pseudo-second-order kinetics with correlation coefficient (0.99 <). The results showed that the modified adsorbent could be used as a suitable adsorbent with a high adsorption capacity for dye removal from water.