Abstract
The carbonized hollow fiber membranes were prepared through gelation of polyamic acid solution, imidization and carbonization of polyamic acid (PAA) gel by mainly controlling the gelation conditions. The microstructure of the carbonized membranes was evaluated by micropore volume, which was measured by molecular probe method. The permeation properties of pure CO 2, pure CH 4 and CO 2/CH 4 mixture through the carbonized membranes were measured and analyzed. High CO 2/CH 4 permselectivity was achieved by the carbonized membrane which was prepared under a specific condition (gelation condition: temperature 275 K, pH of coagulant 9.4; carbonization condition: temperature 1023 K, time 3 h). The permeance of CO 2 at 298 K and the activation energy for CO 2 permeation for mixed gas system were almost equal to those for pure gas system in this carbonized membrane. On the other hand, the permeance of CH 4 for mixed gas system decreased in comparison to that for pure gas system due to the hindrance of CH 4 permeation by CO 2 molecules existing inside the micropores, so that the activation energy for CH 4 permeation increased and the CO 2/CH 4 permselectivity for mixed gas system was greater in comparison to results from pure gas permeation. It was found that the micropores of 0.43–0.50 nm played a very important role to create high CO 2/CH 4 permselectivity.
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