Abstract
The exchange of boron between BF3(g) and BF3·phenol(l) was studied. The single-stage isotopic fractionation factor varied according to the equation, logα= (10.315/T) —0.02423, over the temperature range —8°C to 37°C. B10 is concentrated in the liquid phase. Vapor-pressure measurements of dilute and concentrated solutions of BF3 in phenol were made at various temperatures from —10°C to 40°C. The freezing point of the BF3·phenol complex was approximately —15°C; that for the BF3·2 phenol, —5°C.
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