Abstract
Brush-type chiral stationary phase CSP 12 was specifically designed for separation of BINAPO enantiomers, which can be useful as organocatalysts or as chiral ligands in organometallic catalysis. This chromatographic separation process can compete with other routes to enantiomerically pure BINAPO.
Highlights
Separation of enantiomers of axially chiral compounds is becoming an ever more important goal in chiral chromatography
Brush-type chiral stationary phase chiral stationary phases (CSPs) 12 was designed for separation of BINAPO enantiomers, which can be useful as organocatalysts or as chiral ligands in organometallic catalysis
The work in this field follows from the growing application of chiral compounds in the enantiomerically pure form as chiral organocatalysts or chiral ligands in organometallic catalytic complexes.[1,2,3,4]
Summary
Separation of enantiomers of axially chiral compounds is becoming an ever more important goal in chiral chromatography. Abstract Brush-type chiral stationary phase CSP 12 was designed for separation of BINAPO enantiomers, which can be useful as organocatalysts or as chiral ligands in organometallic catalysis.
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