Abstract
AbstractA novel pressurized capillary electrochromatography (PCEC) was developed to separate basic drugs on strong cation exchange (SCX) column. The separation result by using PCEC was better than that by using micro‐HPLC. The effects of electrical field and pressure on plate height and resolution were investigated. Influence of organic modifier, ionic strength and pH value of buffer on retention behavior were evaluated, and the separation mechanism was also discussed.
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