Abstract

In this work, ionic liquids (ILs) are proposed as candidates for extractive removal of 2-phenylethanol (PEA) (well-known rose-like aroma compound) from its aqueous solutions. Four ILs based on different cations, namely, 1-hexyl-1-methylpyrrolidinium, 1-hexyl-1,4-diaza [2.2.2]bicyclooctanium, 1-(2-methoxyethyl)-3-methylimidazolium, and 1-(2-methoxyethyl)-1-methylpyrrolidinium, and bis(trifluoromethylsulfonyl)imide anion were under study. Thermodynamic data at ambient pressure are presented for pure ILs (including temperature-dependent density data and thermal characterization with DSC) as well as for binary systems {IL + water} and ternary systems {IL + PEA + water}. For the binary systems, (liquid + liquid) equilibrium phase diagrams were determined in temperature range T = (280–370) K. For ternary systems, (liquid + liquid) equilibrium was investigated at T = 308.15 K. An impact of the cation structure on the studied properties is established. The data obtained are discussed in terms of the selectivity a...

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