Sensitivity and Detonation Characteristics of Selected Nitramines Bonded by Sylgard Binder

Abstract

AbstractFour plastic explosives based on cyclic nitramines and polymeric matrix were prepared and studied. The nitramines were RDX (1,3,5‐trinitro‐1,3,5‐triazinane), HMX (1,3,5,7‐tetranitro‐1,3,5,7‐tetrazocane), BCHMX (cis‐1,3,4,6‐tetranitro‐octahydroimidazo‐[4,5‐d]imidazole), and ϵ‐CL20 (ϵ‐2,4,6,8,10,12‐hexanitro‐2,4,6,8,10,12‐hexaazaisowurtzitane, ϵ‐HNIW). Sylgard 184 was used in the all PBXs prepared samples as a binder. The sensitivities to different mechanical stimuli were determined. The detonation velocities were experimentally measured. Detonation characteristics were calculated by EXPLO5 thermodynamic code. For comparison, standard plastic explosives, Composition C4, Semtex 10, and EPX‐1 were studied. Results showed that the experimental detonation velocities as well as the calculated detonation parameters decrease in the following order: CL20‐sylgard>HMX‐sylgard≥BCHMX‐sylgard>RDX‐sylgard. Calculations by EXPLO5 computer program resulted in detonation velocities close to the experimental ones with 3.1 % maximum difference. Urizar coefficient for the Sylgard binder was calculated from experimental data. An inverse linear relationship between friction sensitivity and heat of detonation of the studied samples was observed. Sylgard binder significantly decreased the sensitivity of all the studied nitramines. Among these prepared samples, the properties of BCHMX‐sylgard are similar to other ordinary plastic explosives.