Sensitive determination of Ag, Bi, Cd, Hg, Pb, Tl, and Zn by inductively coupled plasma optical emission spectrometry combined with the microplasma-assisted vapor generation

Abstract

A technique of vapor generation assisted by a microplasma was used for sample introduction into inductively coupled plasma optical emission spectrometry (ICP OES). Replacing a pneumatic nebulizer with a novel microplasma device improved the sensitivities of analytical signals for Ag, Bi, Cd, Pb, Tl, and Zn (by 2–13 times), as well as a concomitant reduction in their detection limits (DLs). Moreover, an outstanding improvement (30-fold) was achieved for Hg. The factors contributing to the boosted signal intensities were higher analyte fluxes and less water vapor produced by the microplasma system. The DLs of Ag, Bi, Cd, Hg, Pb, Tl, and Zn in microplasma-ICP OES were 0.4, 4, 0.06, 0.2, 2, 5, and 0.2 μg L−1, respectively, and the measurement precision was within the range of 0.7–2.4% (it was significantly improved as compared to that achievable with pneumatic nebulization). The proposed microplasma-assisted vapor generation eliminates the use of toxic reductants, e.g., sodium tetrahydridoborate, and it is characterized by higher resistance to matrix effects from transition metal ions (as compared to chemical vapor generation (CVG) and photochemical vapor generation (PVG)). To validate the trueness of the SAGD-ICP OES method, certified reference materials of lobster hepatopancreas (TORT-2), cormorant tissue (MODAS-4) as well as spiked tap water and seawater samples were analyzed to determine levels Cd and Hg. The standard additions method was used for calibration in both cases. Recoveries of the analytes in the case of the analysis of TORT-2 and MODAS-4 samples as well as the spiked tap water and seawater was within the range of 98–113%, which indicated that the developed sample introduction system can be successfully used for very sensitive determinations of selected hazardous elements in environmental samples.