Senegalia Catechu activated carbon incorporated Ba-alginate composite beads for the removal of Safranine B: modeling studies

Abstract

The present investigation depicts the removal of Safranine-Bdye from aqueous solution using senegalia Catechu activated carbon incorporated Ba-alginate composite beads. The alginate beads were synthesized by metal encapsulation technique using BaSO4 as an encapsulating agent. The Safranine-B dye removal efficiency was determinedby the modeling equations like Langmuir and Freundlich. The nature of physical, chemical force of attractionbetween the adsorbate vs. adsorbent and feasibility was determined using pseudo order equations of first andsecond. The progressiveness of the interaction process was predicted by intraparticle diffusion, enthalpy, entropy and Gibbs free energy model equations. Experimentally obtainedoutcomes were implied that the adsorption of Safranine-Bwas feasible for all the parameters used in this study. Furthermore, the predicted diffusion valueswere revealedthat the contact between Safranine-B versus composite beads was well diffused. The surface morphology of virgin and Safranine-B loaded images confirms that the Safranine-B was strappinglybind on outerlayer of the composite. The results of the FTIR spectrum indicatethe Safranine-Bwas intensively attached on thecomposite surface. The TGA result revealsthat the Ba composite bead has predominant temperature bearing nature.