Abstract
β-CuCNS, a three-dimensional polymeric solid with interbonded layers is found to have unusual photoelectrochemical and solid state properties. The material becomes p- or n-type depending on whether CNS or Cu in stoichiometric excess. The n-type is found to be sensitive to the visible spectrum. The methods of preparation of p- and n-type films of β-CuCNS and their photoelectrochemical and solid state properties are discussed. Es wird gefunden, daß β-CuCNS, ein dreidimensionaler polymerer Festkörper mit Interbindungsschichten, ungewöhnliche photoelektrochemische und Festkörpereigenschaften besitzt. Das Material wird p- oder n-leitend in Abhängigkeit davon, ob CNS oder Cu im stöchiometrischen Überschuß vorliegt. Es wird gefunden, daß die n-leitende Species im sichtbaren Spektrum empfindlich ist. Die Methoden zur Präparation von p- und n-leitenden Schichten von β-CuCNS und ihre photoelektrochemischen und Festkörpereigenschaften werden diskutiert.
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