Abstract
State-selected rate constants for predissociation in collinear N 2O( 1Σ +)→N 2( 1Σ + g)+O( 3O) have been calculated by a classical trajectory surface-hopping method. Specific states (tori), corresponding to semiclassical states given by EBK theory, were found by using adiabatic switching. Potential-energy surfaces that cross were assumed since the nonadiabatic interaction is small. Most trajectories on the initial potential-energy surface are quasiperiodic. The rate constants computed for the various tori show fluctuations.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
