Semianalytical solutions of Ising-like and Potts-like magnetic polymers on the Bethe lattice.

Abstract

We study magnetic polymers, defined as self-avoiding walks where each monomer i carries a "spin" s_{i} and interacts with its first neighbor monomers, let us say j, via a coupling constant J(s_{i},s_{j}). Ising-like [s_{i}=±1, with J(s_{i},s_{j})=ɛs_{i}s_{j}] and Potts-like [s_{i}=1,...,q, with J(s_{i},s_{j})=ɛ(s_{i})δ(s_{i},s_{j})] models are investigated. Some particular cases of these systems have recently been studied in the continuum and on regular lattices and are related to interesting applications. Here, we solve these models on Bethe lattices of branching number σ, focusing on the ferromagnetic case in zero external magnetic field. In most cases, the phase diagrams present a nonpolymerized (NP) and two polymerized phases: a paramagnetic (PP) and a ferromagnetic (FP) one. However, quite different thermodynamic properties are found depending on q in the Potts-like polymers and on whether one uses the Ising or Potts coupling in the two-state systems. For instance, for the standard Potts model [where ɛ(1)=⋯=ɛ(q)] with q=2, beyond the θ-point (where the critical and discontinuous NP-PP transition lines meet), a second tricritical point connecting a critical and a discontinuous transition line between the PP-FP phases is found in the system. A triple point where the NP-PP, NP-FP, and PP-FP first-order transition lines meet is also present in the phase diagram. For q≥3 the PP-FP transition is always discontinuous, and the scenario with the triple and θ points appears for q≤6. Interestingly, for q≥7, as well as for the Ising-like model the θ point becomes metastable and the critical NP-PP transition line ends at a critical end point (CEP), where it meets the NP-FP and PP-FP coexistence lines. Importantly, these results indicate that when q≤6 the spin ordering transition is preceded by the polymer collapse transition, whereas for q≥7 and in the Ising case these transitions happen together at the CEPs. Some interesting nonstandard Potts models are also studied, such as the lattice version of the model for epigenetic marks in the chromatin introduced by Michieletto etal. [Phys. Rev. X 6, 041047 (2016)2160-330810.1103/PhysRevX.6.041047]. In addition, the solution of the dilute Ising and dilute Potts models on the Bethe lattice are also presented here, since they are important to understand the PP-FP transitions.