Semi-continuous emulsion copolymerization of vinyl acetate and butyl acrylate in presence of AMPS

Abstract

The emulsifier-free emulsion polymerization of vinyl acetate (VAc) and butyl acrylate (BA) in the presence of 2-acrylamido-2-methylpropane sulfonic acid (AMPS) was carried out by a semi-continuous process. AMPS was a reactive surfactant in the aqueous emulsion, due to its amphiphilic structure and the unsaturated double bonds. Potassium persulfate (KPS) was used as initiator. The following factors were mainly examined: quantity of AMPS, BA and KPS concentrations, which could significantly affect the particle size and its distribution, conversion, gel content, minimum film-forming temperature, etc. The particle size and its distribution were characterized by dynamic laser particle size analyzer, and morphology of the latex particles was characterized by transmission electron microscopy (TEM). Fourier transform infrared spectroscopy was used to characterize chemical structure of copolymers. The results indicated that AMPS was successfully reacted onto the resulted copolymer of vinyl acetate and butyl acrylate. A hydrophilic sulfonic acid group in the molecular structure of AMPS tended to be distributed in particles surface after polymerization. As a result, an electrostatic repulsion between the particles was produced in order to maintain stability of the system. Thermogravimetric analysis curves suggested that as BA content increased, thermal stability of the polymer increased accordingly. The conversion-time plots with varying AMPS and initiator contents were obtained, which illustrated that the initiator concentration could greatly influence the polymerization rate and the final conversion. The TEM micrographs of the final emulsifier-free latex particles for P(VAc/BA/AMPS) system revealed small particle size in monodisperse polymer latex. The particles of the latex were measured as about 150 nm.