Self-sacrificial reconstruction of MoO42− intercalated NiFe LDH/Co2P heterostructures enabling interfacial synergies and oxygen vacancies for triggering oxygen evolution reaction

Abstract

Exploring high-efficiency electrocatalysts for oxygen evolution reaction (OER) is one of the most important concerns to produce hydrogen in water electrolysis. Herein, the FNM/Co2P-0.4 heterostructure was designed as an electrocatalyst for the OER process by the combination of MoO42− intercalating NiFe LDH and Co2P on nickel foam (NF). The surface reconstruction and MoO42− leaching can induce the conversion of Co2P and NiFe LDH on FNM/Co2P-0.4 to generate Co/NiOOH with more oxygen vacancies. Beyond, CoOOH and NiOOH can also synergize to reduce the energy barrier of OER, optimize conductivity, and improve stability. The surface reconstruction and the formation of OOH⁎ were further unveiled by in-situ UV–vis absorption spectra and Fourier-transformed alternative current voltammetry (FTACV). The integration of interfacial synergies and oxygen vacancies can facilitate the adsorption/desorption of intermediates, regulate the d-band center, and expose more active sites. And as a result, FNM/Co2P-0.4 shows a significant low overpotential (240 mV) at 50 mA cm−2, a small Tafel (74 mV dec−1), low activation energy (Ea) and remarkable durability. This work provides a new pathway to improve the OER performance by using interfacial synergies and rich oxygen vacancies derived from the self-sacrificial reconstruction of heterostructured electrocatalysts.