Abstract
This presentation describes two recently developed approaches to electrically active sp/sup 2/ carbon materials (/spl pi/ cluster materials) utilizing self-assembly in well-defined block copolymers: i) control of nanostructure in block copolymers of regioregular poly(alkylthiophenes) and ii) synthesis of nanostructured carbon materials through pyrolysis of self-assembled block copolymer precursors containing polyacrylonitrile. The role of copolymer composition and processing conditions in determining the nanostructure as well as some potential applications of resulting materials are discussed.
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