Abstract
A well-defined six-armed star triblock copolymer s-(PDEA62-b-PMMA195-b-PPEGMA47)6 was synthesized by the core-first ATRP method. The star triblock copolymer shows pH-tunable self-assembly behavior. Interestingly, the reversible vesicle–micelle transition could be achieved by simply adjusting the surrounding pH.
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