Abstract
Mercury(II) complex of 4,5-ethylenedithio-1,3-dithiole-2-thione (C 5H 4S 5), [Hg 2(C 5H 4S 5) 2Cl 4] n, was synthesized and characterized crystallographically. It possesses the one-dimensional polymeric structure composed of centrosymmetric quasi-isolated binuclear subunits. The mercury atoms in zigzag arrangement achieve five-coordination in a distorted trigonal bipyramidal geometry by bonding to two bridging Cl, a terminal Cl, a thione S and a thioether S atom of C 5H 4S 5. The S ... S contacts of 3.568(3) Å between two nearby chains generate a two-dimensional network. Through S ... S interactions of 3.583(3) Å between the two-dimensional layers, a three-dimensional supramolecular network is formed.
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