Self-Shaping Microemulsion Gels for Cultural Relic Cleaning.

Abstract

Cleaning is a foundational and essential operation of protection and restoration of cultural relics, which is also the key step of follow-up works. To overcome the problems of uncontrollable diffusion of cleaning solvents and poor coverage of the cleaning solvent carriers on rough surfaces, here, we propose a strategy of using a self-shaping microemulsion gel that is prepared via emulsifying oleophilic solvents into the specific shear-thinning hydrogel structures. The gel can adaptively cover rough surfaces during the cleaning process coupled with avoidance of unnecessary diffusion of the cleaning solvents, and the mechanical reinforcement of in situ polymerized double-network gels enables its easy peeling off from the surfaces without leaving determinable residues. As a representative demonstration, Paraloid B72, a widely used material for the repair and reinforcement of cultural relics, is employed as a model discolored coating, which can be effectively removed from the rough surface of simulated cultural relics after treatment with the resulting gels. Convincingly, the strategy of constructing agarose/polyacrylamide hybrid double-network gels with shear-thinning and self-shaping performances for the cleaning of cultural relics not only improves the convenience and accuracy of operation but also exhibits an efficient cleaning effect, which will greatly expand the application of microemulsion gels in the cleaning of rough surfaces of cultural relics.