Abstract

Humidity monitoring has become extremely vital in various technological fields such as environment control, biomedical engineering, and so on. Therefore, a substantial interest lies in the development of fast and highly sensitive devices with high figures of merit. Self-powered and ultrasensitive humidity sensors based on SnS2 nanofilms of different film thicknesses have been demonstrated in this work. The sensing behavior has been investigated in the relative humidity (RH) range of 2–99%. The observed results reveal a remarkable response and ultrafast detection even with zero applied bias (self-powered mode), with response and recovery times of ~ 10 and ~ 0.7 s, respectively. The self-powered behavior has been attributed to the inhomogeneities and the asymmetry in the contact electrodes. The highest sensitivity of ~ 5.64 × 106% can be achieved at an applied bias of 5 V. This approach of fabricating such highly responsive, self-powered and ultrafast sensors with simple device architectures will be useful for designing futuristic sensing devices.

Highlights

  • Humidity monitoring has become extremely vital in various technological fields such as environment control, biomedical engineering, and so on

  • The peaks have been indexed in accordance with the JCPDS (22-0951), which confirmed the formation of hexagonal pure phase of S­ nS2 with space group P­ 3m128

  • The hump observed ~ 25° corresponds to the amorphous nature of soda lime glass (SLG) and decreases with increasing film thickness

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Summary

Introduction

Humidity monitoring has become extremely vital in various technological fields such as environment control, biomedical engineering, and so on. Self-powered and ultrasensitive humidity sensors based on ­SnS2 nanofilms of different film thicknesses have been demonstrated in this work. The highest sensitivity of ~ 5.64 × 106% can be achieved at an applied bias of 5 V This approach of fabricating such highly responsive, self-powered and ultrafast sensors with simple device architectures will be useful for designing futuristic sensing devices. Nanoscale materials have been investigated for further improvement in sensing performance in terms of higher sensitivities, and faster response and recovery times. All these sensors require a power supply and in a device which involves a number of such sensors, power supply becomes a huge concern which can lead to incredible cost and complexity. Magnetron sputtering has emerged as a perfect tool for deposition of large-scale thin films, involving ultra-high vacuum, which helps in controlling the thin film properties during deposition

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