Abstract
The template-based methods belong to low-cost and rapid preparation techniques for various nanostructures like nanowires, nanotubes, and nanodots or even quantum dots [QDs]. The nanostructured surfaces with QDs are very promising in the application as a sensor array, also called 'fluorescence array detector.' In particular, this new sensing approach is suitable for the detection of various biomolecules (DNA, proteins) in vitro (in clinical diagnostics) as well as for in vivo imaging.The paper deals with the fabrication of TiO2 planar nanostructures (QDs) by the process of titanium anodic oxidation through an alumina nanoporous template on a silicon substrate. Scanning electron microscopy observation showed that the average diameter of TiO2 QDs is less than 10 nm. Raman spectroscopic characterization of self-organized titania QDs confirmed the presence of an anatase phase after annealing at 400°C in vacuum. Such heat-treated TiO2 QDs revealed a broad emission peak in the visible range (characterized by fluorescence spectroscopy).
Highlights
Semiconductor quantum dots [QDs] with exceptional physical and optical properties are favorable fluorescent markers in medicine, where they can serve as biosensors and labels in biological imaging [1,2,3]
Anodization process Ordered arrays of titania QDs were achieved by successive anodization of aluminum and titanium layers using the utility model equipment for electrochemical postprocessing deposition fabricated in our laboratory
The array of TiO2 QDs for biosensing application was prepared through a one-step anodization technique using a nanoporous alumina template
Summary
Semiconductor quantum dots [QDs] with exceptional physical and optical properties are favorable fluorescent markers in medicine, where they can serve as biosensors and labels in biological imaging [1,2,3]. QDs are used in colloidal form (in aqueous solution) [4,5]. Directly grown QDs in planar form (so-called lab-on-chip) for in situ biosensing purposes are studied very rarely [6]. The scientists try to encapsulate the colloidal QDs in some matrix, e.g., from polymeric compounds [7]. The deposited nanostructures are mostly fabricated through traditional top-down patterning methods like epitaxy or lithographic techniques (mainly photolithography and e-beam lithography), which are expensive and time-consuming. Contrary to these methods, the template-based technique seems to be more convenient for nanostructured material synthesis since it is affordable and provides reproducible results.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have