Self-heating and fatigue crack growth behavior of reinforced NR/BR nanocomposites with different blending ratio

Abstract

Fatigue crack growth and dissipative self-heating due to viscoelasticity are crucial properties of rubber materials under dynamic service conditions. Systematic evaluation of the thermo-mechanical coupled fatigue properties with suitable lab testing methods could contribute to the development of long-lasting and robust elastomer materials. In this work, on the one hand, the hysteresis energy density, thermal conductivity, and surface temperature rise, which are closely related to the self-heating generation rate, heat transfer rate and heat build-up of the carbon black reinforced seven different natural rubber (NR) and polybutadiene rubber (BR) blends were measured. A thermo-mechanical coupling simulation method was used to reproduce the experimental observation. On the other hand, the fatigue threshold (T0), critical tearing energy (Tc), and fatigue crack growth rate (FCGR) under different tearing energy were investigated by using the advanced rubber fatigue instruments. The Lake-Lindley model was utilized to describe the rubber fatigue responses from the intrinsic strength to the ultimate strength. The results show that the dissipative self-heating of NR/BR:30/70 blend is the most obvious one, which could be well explained by the simulation results. The T0 shows an upward trend while Tc shows a downward trend with the increasing blend ratio of BR. The existence of carbon black fillers showed tiny effect on T0 of NR, but significantly enhanced the T0 of BR. The FCGR of reinforced NR/BR nanocomposites have Lake-Lindley law responses that cross over each other. Therefore, which rubber material is superior to others in resisting crack propagation depends on the magnitude of the input tearing energy.