Self-healing polyurethane elastomer with ultra-high mechanical strength and enhanced thermal mechanical properties

Abstract

Polyurethane (PU) materials are widely used due to their excellent comprehensive properties including high strength, good wear resistance and weather resistance. To further improve the service life and safety of polyurethane materials, self-healing polyurethane materials have been developed. However, self-healing polyurethane generally suffers from low mechanical strength and poor thermal mechanical properties. Here, we have constructed a strong dual network by introducing benzene-1,4-diboronic acid (PDBA) into poly(urethane-urea) (PUU). On one hand, PDBA can form coordination bonds with nitrogen atoms in PUU, leading to the formation of a dual network consisting of boron-nitrogen coordination and hydrogen bonding. This dual network imparts PUU with a maximum tensile strength of 84.2 MPa. On the other hand, boron-nitrogen coordination is more stable than hydrogen bonding at high temperature, thereby significantly enhancing the thermal mechanical properties of PUU (the mechanical strength of PUU-PDBA-50 % and PUU-PDBA-100 % increased by 1.8 times and 2.4 times, respectively, compared to PUU at 100 °C). Meanwhile, the dynamic nature of the dual network endows the material with self-healing ability.