Self-healing performance and rheological properties of styrene-butadiene-styrene block copolymer modified asphalt promoted by polyurea elastomers containing disulfide bonds

Abstract

Self-healing asphalt is considered as one of the desirable methods to extend the service life of asphalt pavement. This research prepared a polyurea elastomer containing dynamic disulfide bonds (PUA)/styrene butadiene styrene block copolymer (SBS) composite modified asphalt. Moreover, a new asphalt self-healing performance evaluation method based on the damage process and results has been proposed. Subsequently, the self-healing ability of PUA, the distribution of modifier, the functional group and molecular weight of composite modified asphalt were characterized by fluorescence microscope, Fourier transform infrared spectroscopy (FTIR) and Gel permeation chromatography (GPC). The self-healing potential and limits of PUA/SBS composite modified asphalt was investigated through the proposed healing linear amplitude scanning (HLAS) test. Results show that the SBS content and fatigue load level are the main factors affecting the self-healing promotion effect of PUA. The critical point of healing fatigue strain (HFS) can indirectly characterize the threshold at which healing promoters exert their effects. Next, the addition of fillers will reduce the self-healing performance of PUA/SBS composite modified asphalt, but it still improves by at least 61.318% compared with SBS modified asphalt. Finally, the addition of self-healing elastomers (PUA) improves the permanent deformation resistance at high temperature and low-temperature crack resistance of SBS modified asphalt. The dynamic recombination of disulfide bonds can increase the fatigue cycle number of 4%SBS modified asphalt by 93.52% at a 5% load strain level.