Abstract

Elastic constants of strongly anharmonic nonionic dielectric crystals are studied within the pseudoharmonic approximation by means of two-time Green functions. The relation between the method of homogeneous deformation by Leibfried and Ludwig and that of long waves is investigated. These considerations lead to a generalization of the method of homogeneous deformation for the case of strongly anharmonic crystals. A comparison between the results of the two methods shows that the pseudoharmonic approximation satisfies the exact elastic sum rule.

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