Abstract
FDTD simulations of the Maxwell equations are combined with the multi-fluid plasma equations to study the dynamics of a high power microwave discharge in air. The breakdown takes place in a short time of a few nanoseconds and the concentrations of electrons, ions, excited species, and the dissociation products are quickly enhanced. The breakdown time decreases with decreasing of the pressure and the pulse amplitude, while increases with increasing of the pulse width. N2+ and O2+ are the most important positive ions, whereas O− is the most populated negative ion. For a single microwave pulse, the electron number density is large up to 1 μs, and the dissociation and excitation continue to increase the small radicals and excited species. Then the electron number density drops and the population of excited species declines. The ozone production becomes important after 1 μs when the three body association of O and O2 dominates over the dissociation processes. The ozone number density continues to grow up to 5 ms, and then saturates at a value of 1022 m−3. Quenching of electronically excited nitrogen molecules by O2 molecules and the subsequent dissociation to atomic oxygen and generation of NO, are found to be important and can play a significant role in the ultrafast gas heating.
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