Abstract

Normal 0 Novel complexing process in the Zn(II)– ethanedithioamide– ethanedial triple system proceeding into nano -reactors of zinc(II)hexacyanoferrate(II) gelatin-immobilized matrix systems under a contact with aqueous-alkaline (pH~12) solutions containing ethanedithioamide and ethanedial, has been studied. It has been shown that self-assembly (template synthesis) of supramolecular (555)macrotricyclic Zn(II) coordination compound with chelating ligand 2,7-dithio-3,6-diazaoctadien-3,5-dithioamide-1,8,occurs under such specific conditions. Besides, ethanedithioamide and ethanedial act as ligand synthons in this process.

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