Self-Assembly of Silicon@Oxidized Mesocarbon Microbeads Encapsulated in Carbon as Anode Material for Lithium-Ion Batteries.

Abstract

The utilization of silicon/carbon composites as anode materials to replace the commercial graphite is hampered by their tendency to huge volumetric expansion, costly raw materials, and complex synthesis processes in lithium-ion batteries. Herein, self-assembly method is successfully applied to prepare hierarchical silicon nanoparticles@oxidized mesocarbon microbeads/carbon (Si@O-MCMB/C) composites for the first time, in which O-MCMB core and low-cost sucrose-derived carbon shell not only effectively enhance the electrical conductivity of the anode, but also mediate the dramatic volume change of silicon during cycles. At the same time, the carbon can act as "adhesive", which is crucial in enhancing the adhesive force between Si and O-MCMB in the composites. The as-obtained Si@O-MCMB/C delivers an initial reversible capacity of 560 mAh g-1 at 0.1 A g-1, an outstanding cyclic retention of 92.8% after 200 cycles, and respectable rate capability. Furthermore, the synthetic route presented here is efficient, less expensive, simple, and easy to scale up for high-performance composites.