Abstract
Two novel polyoxovanadate (POV)-containing fluorosurfactants, each with two hydrophobic fluorinated "tails" and one nanosized, hydrophilic, rigid POV "head group", are synthesized for the first time. They self-assemble into spherical, bilayer vesicles in acetonitrile/water mixed solvents, as evidenced by systemic studies using laser light scattering (LLS) and electron microscopy techniques. The vesicle sizes demonstrate dynamic change over different solvent compositions mainly as a result of the solvent swelling of the fluorocarbon chains, although the charge number on the POVs changes over the solvent polarity as well.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Langmuir : the ACS journal of surfaces and colloids
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.