Abstract

Two Zn–Ln rectangular nanoclusters [Zn8Ln4L8(OAc)8](OH)4 (Ln = Sm (1) and Nd (2)) with sizes of 9 × 19 × 28 Å were constructed using a long-chain Schiff base ligand built around a flexible (CH2)3O(CH2)2O(CH2)3 backbone, and their visible and NIR luminescence properties were determined.

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