Abstract

AbstractA new series of hydrogen bonding‐driven heterodimers have been self‐assembled in chloroform from hydrazide‐based monomers. Additional intermolecular donor‐acceptor interaction between the electron‐rich bis(p‐phenylene)‐34‐crown‐10 unit and the electron‐deficient naphthalene diimide unit has been utilized to increase the stability of the dimmers, and pronounced cooperativity of the two discrete non‐covalent forces to stabilize the dimer has been revealed by the quantitative 1H (2D) NMR and UV‐Vis experiments.

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