Abstract

AbstractThe cover picture shows the self‐assembly of a tetranuclear CoIII metallacycle from the reaction of a bis(benzene‐o‐dithiolato) ligand and CoII after aerial oxidation. Two differently coordinated metal centres (syn and anti) are observed in the metallacycle even though a ligand with two identical donor sites has been used. This unusual structural motif is formed in order to avoid strong steric interactions between the ortho‐sulfur atoms, which would result in a hypothetical dinuclear complex. Details are discussed in the article by F. E. Hahn et al. on p. 535 ff.

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