Self-assembled Ti3C2Tx membrane driven by Marangoni effect for anti-corrosive and anti-wear applications

Abstract

The recent rise of Ti3C2Tx has extended the applications in epoxy resin due to its large specific surface area and excellent mechanical properties. Whereas, the synergy between epoxy and Ti3C2Tx restricts properties enhancements when Ti3C2Tx is subjected to random orientation and discontinuous distribution. To optimize the barrier and lubrication characteristics of Ti3C2Tx, we have successfully prepared Ti3C2Tx membrane by using the Marangoni effect self-assembled method to move Ti3C2Tx nanosheets to the same latitude and deposit them on epoxy resin for the first time. Meanwhile, micro-arc oxidation technology was adopted to enhance the bonding strength of the substrate with epoxy. Due to the effective corrosion resistance offered by the Ti3C2Tx membrane, even after 28days of immersion, the pure epoxy coating had completely failed, while the |Z|0.01Hz value of the multilayer coating still increased by 36.5 % compared to MAO/EP/EP. Furthermore, the wear rate and the friction coefficient reduced by 58.2 % and 21.4 % in comparison to the pure epoxy coating. This exceptional lubrication property stems from the interlayer shear sliding of the expansive Ti3C2Tx nanosheets, effectively preventing direct contact between the friction ball and the epoxy.