Abstract

Abstract A solution-phase synthesis of lipid-packaged mixed valence platinum complexes is newly developed. Addition of aqueous HAuCl4 or AuBr3 to Pt(en)2[1]2 complex dissolved in dichloromethane affords halogen-bridged linear complexes [Pt(en)2][Pt(en)2X2][1]4 (X = Cl or Br). Formation of self-assembled nanowires was confirmed by transmission electron microscopy and X-ray photoelectron spectroscopy.

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