Abstract

A metallo-organic hybrid acid namely tetra-aquo bis-4-carboxy- N-phthaloylglycinato zinc(II) dihydrate is prepared and characterised. In this complex the hydrogen bonding by free carboxylic acid group and π–π interactions between the rings in crystal lattice contributes to the formation of self-assembled structure. A monomeric nickel complex from 2-carbomethoxy benzoic acid ( L2H) and pyridine [Ni( L2)(py) 3(H 2O) 2] L2 is prepared (where py = pyridine). This complex has ionic as well as monodentate carboxylates. It forms self-assembly by C–H⋯π as well as hydrogen-bonding interactions. The 2-carbomethoxy benzoic acid ( L2H) forms dimeric copper complex [Cu 2( L2) 4(H 2O) 2]2H 2O which has an extended chain structure through hydrogen-bond interactions.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.