Abstract
AbstractSelenium dioxide is traditionally regarded as an oxidant and rather as a selenium source for making organseliums. Herein, we developed a new selenation method by using selenium dioxide instead of commonly used selenium powder or diselenides to generate Se‐substituted imidazoheterocycle and aniline compounds. Furthermore, sodium arenesulfinates were selected as coupling partners instead of traditional aromatic halides. All reactions give desired products in moderate to excellent yields under mild conditions.
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