Abstract

A high-resolution synchrotron photoemission study of selenium, selenophene (Seph), and benzeneselenol (BSe) adsorption on a Cu(100) surface was performed, to investigate the film structure, chemical adsorption properties, and molecular orientation. Complementary measurements for selenophene adsorption on Au(111) were also performed. The investigation is based on determination of core level binding energies (CLBEs) by X-ray photoelectron spectroscopy (XPS) and near-edge adsorption fine structure (NEXAFS). Se chemisorption was studied as a complement to the work on molecules in order to obtain data on the CLBEs for the atomic case. Se adsorption was performed from a Na2Se solution and thereafter annealing in vacuum. Annealing leads to appearance of ordered structures in LEED. Se 3d CLBEs were determined for the different cases. Fits of Se 3d XPS spectra show existence of several components attributable to different adsorption configurations. Also coadsorption with S was studied, which leads to changes in ad...

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