Abstract
In the copper-antimony-sulfide (Cu-Sb-S) system, four major phases (CuSbS2, Cu3SbS3, Cu3SbS4, Cu12Sb4S13) exist and are known to have good potentials as absorbers. To form thin films of Cu-Sb-S using a non-vacuum hybrid ink, Cu and Sb precursors were coated and sulfurized with a rapid thermal annealing (RTA) process. According to the ratio of Cu and Sb (Cu/Sb), different Cu-Sb-S thin films (CuSbS2 vs. Cu3SbS3, Cu3SbS4, Cu12Sb4S13) were easily obtained and confirmed by X-ray diffraction (XRD). However, although the Cu/Sb ratio of the hybrid ink was the same, different phases (Cu3SbS3, Cu3SbS4, Cu12Sb4S13) were observed depending on the reaction temperature, time, and pressure. It was shown that the reaction temperature, time, and pressure were also important factors for obtaining thin films. The sulfurized conditions to achieve thin films with a target phase were compared against different Cu/Sb ratios, reaction temperatures, reaction times, and chamber pressures.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.