Abstract
AbstractNew fluorinated alicyclic β‐amino ester stereoisomers with a cyclohexene or cyclohexane skeleton were prepared from cis‐ or trans‐2‐aminocyclohex‐3‐enecarboxylic acids in five or six steps through a regio‐ and stereoselective hydroxylation and hydroxy–fluorine exchange. Fluorinated aminoester enantiomers were synthesized from enantiopure cis‐ or trans‐2‐aminocyclohexenecarboxylic acid (prepared byenzymatic resolution of the racemic substances).
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