Abstract

We demonstrate selective photo-reactions observed between the two different chemical species bearing carbon-carbon double bonds in MOF 1. 1,2-Bis(4-pyridyl)ethylene (bpe) was fixed in 1 as the organic linker, which reacted with tetramethylethylene (TME) as the guest molecule. As a result, a specific product from the radical reaction was selectively generated, whereas various side products were observed when reacted in solution. Our strategy to realize selective reactions would contribute to enforce the applicability of solid-phase reactions in synthetic chemistry.

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