Abstract
Abstract Electrochemical and spectroelectrochemical experiments at an ITO electrode clarified that O=FeIV(4-TMPyP) was formed via 1e− + 1H+ oxidation process of FeIII(4-TMPyP) in pH 7.4 PBS and the electrogenerated O=FeIV(4-TMPyP) selectively reacted with NO to give NO2− as the final product through an electrocatalytic cycle.
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