Selective enzyme impregnation of chips to reduce specific refining energy in alkaline peroxide mechanical pulping

Abstract

Abstract Eucalyptus wood chips were impregnated with various blends of fiber modifying enzymes prior to preconditioning refiner chemical-alkaline peroxide mechanical pulp processing. The process includes chemical pretreatment and two stages of refining. The energy consumption was compared at the same Canadian standard freeness level of 350 ml. Some enzyme treatments were found to reduce specific refining energy (SRE) by at least 24%. The enzyme hydrolysis within the cell wall was observed by transmission electron microscopy of impregnated chips with high spatial resolution. The enzyme blends that successfully reduced SRE requirements were found to selectively loosen the bonds between the S1 and S2 layers of the fiber wall. Enzymes which selectively attached the S2 layer did not impart any SRE reduction. All experiments for impregnation and pulp processing were conducted at the Andritz Pilot Plant in Springfield, OH.