Abstract
The rate of protium-deuterium exchange, catalyzed by deuterated Raney nickel, on all carbon atoms of four inositols, was measured. The rate of exchange is lowered by methylation of an adjacent hydroxyl group; this effect was studied on seven isomeric, inositol methyl ethers. Correlations between the rate of exchange and the configuration, the conformation, and the site of O-methylation of the inositols have been established.
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